Posts Tagged ‘lake pigments’

How to Make Madder Lake, part 2

January 9, 2015

Previous post: How to Make Madder Lake, part 1.

The second secret.

There’s actually another little ‘secret’ to making madder lake, this one a bit more of an open secret, but something very important to keep in mind. It is this: you can’t just boil madder up the way you can with carmine lake or most other dyestuffs. The alizarin color in madder is destroyed by high heat, so you can’t turn the temperature up over 170ºF or thereabouts. However, the dye will not emerge from the roots unless it’s heated, so your job is to get the temperature up to between 120ºF and 140ºF, and keep it there.

(Note: the vulnerability of madder to high heat is something I’ve read from numerous sources. However, more than once I’ve accidentally allowed the temperature of the dyebath to briefly stray up toward 200 degrees, and it hasn’t seemed to hurt the resulting color much. There are many different experiments I have in mind for madder lake production in the future; one of those experiments is to give the dyebath a really good boil, to see if it really does kill the color or not. But for the time being, I’m following the recommendations about temperature control as well as I can.)

Here’s the procedure:

After the last soak and straining, put the wet roots into a cooking pot big enough to hold them, and cover the roots with water – this will be henceforth referred to as the ‘dye bath’. Water: the first time I did this, I used distilled water for everything. It wound up being a lot of distilled water! Nowadays I just use tap water, and it seems to be fine. If you want to be a bit more careful, use distilled water for the initial dye bath, and then regular old tap water for everything else.

Then make a double boiler by putting this pot into a larger pot that also contains water. This way you’ll be able to control the temperature more easily. Also: the bigger the pots in question – and more specifically, the more water is in them – the easier it is to control temperature and keep it steady. Here I have this contraption cooking low on a gas stove:

Madder Double Cooker

Madder Double Cooker

A thermometer goes into the dye bath. Here I’m using a big thermometer I bought at a beer brewing supply shop – another activity that requires good temperature control! (I have acquired a slow cooker with temperature control, at some point I will try making madder lake in this, rather than the makeshift double boiler.)

Yet another little ‘secret’ to making madder: it takes a while! Cooking up carmine or weld lake takes an hour, maybe two; madder takes a couple of days at its lower temperature. At night, or when I’m out of the house, I cover the pot and turn the stove off, and turn it back on first thing when I wake up or return home. You may need to add extra water periodically to one pot or the other.

I cook the roots for about a day, then add alum to the dye bath. Alum: in my previous posts, I wrote that we were beginning with 10g of alum, but that was an error – I was confusing two different recipes in my head. I’m actually using 30g of alum here. I’ve corrected the other posts.

Take the 30g of alum and pour it into the dye bath. I like to dissolve the alum in its own warm water before adding it in, but this isn’t necessary. Then cook the dye for another day or so.

When you dip a piece of paper or paper towel into the dye bath after a few days, it should now come out a juicy, rich red. In the pic below, you can see how red the bath looks after a couple of days. This is the red you want, the alizarin! Time for the next step.

Madder Dye Bath

Madder Dye Bath

How to Make Madder Lake, part 1

December 26, 2014

Previous post: Preparation for Making Madder Lake.

In the last post, I wrote that we’re beginning with about 100g of madder root and about 30g of potash alum. I also wrote that there was a big secret coming in this one. Well, read on!

Most madder recipes I’ve seen online – including this one from Rubio Violins, which is the one I think most home chemists follow – have us putting the madder roots into water and cooking them up directly. These recipes leave out a crucial step, which is to wash the roots beforehand. One or two sources actually mention this washing, but do not mention the purpose of it, which is to remove extraneous dyes and other colors that the roots contain, and which will contaminate our lovely rose color if we leave them in there. So ‘washing’, in this case, means giving them a good soak, and then throwing out the bath water (without the baby, which is the rose dye that will not emerge until the roots are heated). Here I’ve got my roots soaking in water out of doors.

Madder Roots Soaking

Madder Roots Soaking

I soak these roots for several days. It’s best to do this when it is relatively cool outdoors, as I’m doing here. As the madder roots rest, they ferment, so you’re likely to see some bubbles or foam on the surface at some point. If it’s too warm out, a lot of mold will be generated as well. I don’t think this mold actually interferes with the making of the pigment, but it does make it a little difficult to see what’s going on in there. (Also, if it’s really hot, it might actually start cooking some of the alizarin dye out of the roots, and you definitely don’t want that yet.) So if it’s really warm out when you’re making your lake, consider moving the roots out of the sun – maybe even put them in the garage or something.

When the roots have been sitting for several days, the water should look reddish gold. At this point, dump out the water. Yes, you read that right – dump it out! Do it! I know it looks like there’s a lot of color in there that you want to be saving and using. Trust me: it’s no good. It’s just contamination. It is exactly this stuff you’re looking at that makes the finished madder lake brown instead of rose. So dump it.

This is the big secret.

Keep going at this point: refill the pot with water and strain a few times, until it comes out fairly colorless. Then soak overnight again. Then empty and strain, then soak overnight. Keep doing this until there’s not much color coming out of the water. (The purple gunk doesn’t matter – that’s from the root bark.) This entire process may take a week, or even longer. Be patient: a good madder lake is worth the wait. At some point the emptied water will start to look clearer and more pink. Once that happens, we’re ready to make our madder lake.

To be continued!

Preparation for Making Madder Lake

December 1, 2014

(The good stuff!)

It’s time to make these posts at last, after many delays: How to Make Madder Lake.

I’ve posted before about how to make a lake pigment – check this post here – and will make more posts about it in the future: about the different varieties of carmine lake, and how to make a proper yellow lake from weld, and so on. But madder lake is, well, different. It’s more involved to make a quality red lake from this dyestuff. Many have tried making madder lakes, only to be disappointed in the reddish-brown color that results, and have wondered how to make that exciting rose color we all love. As it turns out, there is one little secret that makes all the difference.

Some history: madder lake is one of the older lake pigments, found to have been used on some rather ancient objects. But for most of the Middle Ages, some of the other red lakes – lac, brazilwood, etc. – were often preferred over madder. As Daniel Thompson puts it: “To make as good a lake from madder as any beginner can make from brazil wood calls for a good deal of expert chemical knowldege and careful manipulation; and there is no evidence to suggest that medieval colour-makers possessed the knowledge necessary to making good madder lakes.” (The Materials and Techniques of Medieval Painting, Daniel V. Thompson.) Madder lake, as an artist’s material, really came into its own in the Renaissance, being used as a glazing color for drapery and so on. Its popularity continued through the Baroque, Classical, and Romantic eras; one of its popular functions was as a glaze over vermilion in drapery, creating an intense and fairly stable red.

In the Nineteenth Century, a process was discovered to make a very rich and powerful rose color from madder, using sulfuric acid. (There are some sources that report that this is when madder lake was invented; this is not true. It was this more powerful madder lake that was created at this time, a color named rose madder. It is this recipe, given by George Fields, that Winsor & Newton claim to still be using today.) We won’t be using sulfuric acid in this recipe, but we will still be able to make a nice rose-red madder lake by taking our time and following a procedure.

Making madder lake may be more involved and time-consuming than some of the other lake pigments, but the results can be well worth the investment. Not only is it one of the most beautiful lakes, and an absolute joy for skin tones, but it is also, by all accounts, far more lightfast than any other natural lake pigment. It is the only natural lake, as far as I am aware, that is still in general use by artists, because it is the only one that is considered permanent enough for artistic use (at least as an oil paint). The stuff may not last forever, but it will last, as the man said, a goodish while. And, unlike the synthetic alizarin crimson, when it does fade it appears to fade slowly and gracefully over time, rather than disappearing all at once.

The ingredients are simple and few: some madder root; potash alum; sodium carbonate (washing soda) or potassium carbonate (potash); and water. We’ll also need a slow cooker – or a little double-boiler setup that I’ll show later on – a thermometer, a large jar or two, some coffee filters and a funnel. The coffee filters: get some of the big flat-bottomed basket filters, not the cone-shaped ones – those have a tendency to spring leaks.

We will begin with about 100g of roots, and about 30g of alum. This will make a small amount of lake pigment. Stay tuned – the big secret comes in the next post!

Madder roots

Madder roots

Sap green

July 10, 2011

I’ve been neglecting the blog, because I’ve been insanely busy with getting my portfolio together, building my site, etc. But I’ve been experimenting with this and that as I’ve had time. Some of my recent adventures: an anthocyanin blue from geranium blossoms; an iron weld lake; shopping for a dragon’s blood tree; studying carmine in the wild; the first really successful madder lake from my garden plants (and figuring out how to make a dark and a light madder lake from the same batch); and the finding and purchasing of a natural-lake oil paint, from a very mainstream company, that has been out of circulation for most of a decade. I’ll share all that stuff with you, but for today I’ve prepared an article about sap green:

Sap green is a traditional color that enjoyed popularity from medieval illumination all the way through the Romantic era of watercolor painting. It is a warm, yellowish green, transparent, tending toward olive in masstone and a brighter, livelier green in tints. As an artist’s color it has been quite useful to many artists, filling in a difficult mixing area of the color wheel, supplying beautiful and interesting transparent green shadows, and lovely mixtures for foliage. It is fugitive, of course, like most natural organic colors, which is why it fell from vogue in the nineteenth and twentieth centuries, when modern synthetic greens that were more lightfast became widely available.

The color sap green is derived from the berries of the buckthorn plant. The usual plant used was rhamnus cathartica, or common buckthorn, which is found in the British Isles. The cathartica part of the species name refers to the fact that the buckthorn berries can be used as an emetic, and the plant is often mentioned in older medicinal treatises.

Sap Green - © MFA Boston

Sap Green - © MFA Boston

The dyestuff in Northern Europe is common and economical, and yields a beautiful color – small wonder it was popular for so long. The plant has been naturalized in parts of North America, and has become quite a problem in those areas, because common buckthorn can be very invasive. It spreads rapidly and aggressively, has no natural enemies on this continent, and quickly takes over an area of woodland, squeezing out the natural flora, and in the process some of the natural fauna as well, as they lose their traditional food sources to the invader. My original excitement to try growing this plant was dampened considerably upon learning of the problems associated with it.

I’m quite a fanatic about natural colors, of course; so, while I am an adamantly against risking introducing an invasive species into the ecolocality in which I live, I nevertheless spent some time in negotiations with myself. The common buckthorn is invasive in much cooler and wetter areas than southern Californa; there is little way the plant could be as successful here. In any case, the plant reproduces sexually and needs both a male and a female plant to spread; I’ll just get one plant, I reasoned, and so I’ll be safe. But in the end, I decided sadly that it just wasn’t worth the risks. I want to grow plants that can have a future in my garden and others – common buckthorn clearly doesn’t fit the mold, at least not on this continent. (The closest thing I have to an invasive species is madder, which is spreads agressively through root runners. But madder I feel confident I can control by killing it off if necessary, mainly because the birds and other animals of the area are not interested in its berries or seeds, so the chances of it spreading without my knowledge are greatly reduced. Common buckthorn does not have that element of safety; its berries are enjoyed and spread by many varieties of bird.)

If you happen to live in an area that has been invaded by common buckthorn, you have every opportunity to make some real sap green; for goodness sake go out and pick some berries. Every berry you use is one that cannot spread the species further.

There is another, non-invasive species of buckthorn that is actually much better suited for the hot and dry weather of California, being from the Mediterranean area of the Old World: rhamnus infectoria (or rhamnus saxatilis), the same buckthorn that is used to make stil de grain yellow lake. While a green can be made from the berries of this plant (depending on how ripe they are), it is much better used as a source of the lovely yellow stil-de-grain. You can get the berries from dye shops. I’ve been thinking of getting some seeds and growing a shrub in my garden plot; unfortunately, they seem a bit difficult to come by.

This is one of several posts I’ll make concerning the importance of localism in thinking about the sustainability of artist’s colors. If I lived in Northern Europe, sap green would be a primary color on my watercolor palette. Here in the American Southwest, it can’t be.

Lightfastness Anxiety Disorder

May 1, 2011

I think it is very beneficial to learn as much as possible about art materials, and how to construct a sound oil painting, and which commercial materials are to be preferred or avoided for this purpose. The last thing you or your buyer wants is a painting that crumbles to the floor when someone slams the front door too hard. But I also sometimes feel that artists of today are rather more concerned about “permanence” than they need to be. That’s putting it a bit mildly; at times it seems that many artists’ concern over lightfastness in particular has reached a fever pitch. And yet, the fact is that real permanence in an oil painting is impossible! No matter what colors you use, your oil painting will not last forever. If you’re painting on stretched canvas, your painting will probably not last more than a few centuries at most. If you’re adding many adjunct ingredients as mediums, then quite possibly considerably less than that. If future generations decide that your painting doesn’t merit conservation efforts, then almost certainly less than that. Many oil paintings created this year will likely crumble and be thrown out before the permanence of any color commercially sold today becomes a real issue. And yet, so many artists today are worried about lightfastness. I sometimes, with affectionate exasperation, refer to this obsession as Lightfastness Anxiety Disorder (LAD).

Artists of the past don’t seem to have suffered from this disorder. It was common for artists of the past to use colors that today are widely considered to be impermanent, fugitive, and even “unfit for artistic use.” This doesn’t mean that artists of the past didn’t know what they were doing, and it certainly doesn’t mean that they didn’t care about their art. Quite the opposite. I personally think that they were focused on the right things, and didn’t spend a lot of time worrying about trying to make an oil painting last forever.

At Ivy Ranch

At Ivy Ranch

Just as importantly, many artists of past eras simply knew how to use less permanent colors in the safest possible ways. Take the natural lake pigments: madder, carmine, weld, etc. In oil paintings the natural lake pigments were most commonly used as glazes, over underpaintings that had been completely modeled using more permanent colors. This way, if or when they faded, their doing so would not break the painting in any fundamental way. Take a look at the painting on the right, At Ivy Ranch, which I recently completed. The forms of the couch were glazed with two coats of rose madder genuine by Winsor & Newton. If the lake color ever fades, the drapery will still be there, because it was painted in very permanent earth colors, bone black and lead white. Then, if a conservator (or any reasonably competent professional artist, hired by some future owner of this painting) wishes to retouch or even completely reapply the glaze, it will be an easy matter to do so: no modeling required, just slap another glaze layer on there. (In the case of the conservator, this reapplied glaze would be done with a removable resin paint, rather than an oil paint.)

At Ivy Ranch - no madder

At Ivy Ranch - no madder

A benefit to working like this is that I can see exactly what the painting will look like if the glaze happens to fade entirely at any time in the future. I wouldn’t be able to do that if I used the lake as a regular mixing color. At right is a photo taken from quite early on in the painting process – just some basic value and temperature separations slapped in, the only parts that had been worked up at all were the skirt and the couch. The couch wound up going a bit farther than this before the glazes were applied, particularly in that the area behind the girl became a much darker shadow accent. But aside from that, this is somewhat like what the painting would look like if the madder glaze were to fade completely from the picture. Unlikely to ever happen, of course; rose madder, for all its notoriety lately among those afflicted with LAD, is actually a fairly durable pigment. (Surprise!) More likely is that the madder, over the course of decades and centuries, will fade to some extent; and so much later on you might instead see something like this:

At Ivy Ranch - simulated fading

At Ivy Ranch - simulated fading

Not my first preference – but not the end of the world either. And again, that madder glaze could be rather easily reapplied at any point in the future, and even more than once if need be.

Certainly the safest natural lake pigment to use is madder, and the safest way to apply it is in a full-strength glaze, as I’ve done in this painting. Many artists of the past were quite content to regularly use colors far less permanent than madder; but even for artists of today, with higher standards of lightfastness, there really should be no problem in my opinion with using madder as I’ve used it here. This is a very safe use of a pigment that is actually reasonably lightfast (ASTM II, suitable for artistic work).

Professional artists have a certain financial responsibility to use quality materials and sound painting practices; but this emphasis on “permanence,” I feel, has gone a bit far. And it almost always seems to revolve around lightfastness, and so seldom around other factors of durability in art materials. It has often amazed me that so many artists eschew the use of madder for “archival” reasons, but then turn around and mix large amounts of natural resins or balsams into their paint layers! … or buy and use the cheapest acrylic-primed canvases they can find, ones which will certainly not hold onto an oil paint layer for very long. I encourage my fellow artists to learn more about the structural aspects of longevity in a painting, and to lighten up – just a little – about lightfastness, and learn some of the ways in which less lightfast colors may be used in relative safety. Rose madder is certainly one of the most gorgeous colors ever to grace the medium of oil painting; and it is, unlike the quinacridones and pyrroles, a sustainable artist’s color. The madder lakes have been used by many, perhaps even most, of the greatest and most celebrated oil painters in history. So go ahead and use a rich glaze of madder on that drapery – why not! You’ll be in very good company.

Take the plunge. You won’t regret it.

Madder lake from the garden

March 6, 2011

I spent the morning in the garden today – some of you are waiting for fresh iris rhizomes, and the weather finally cleared up enough for me to go dig some up. However, as has happened on so many other occasions, the best of intentions were thwarted – by the madder plants. I wanted to replant some of the rhizomes that have been sitting around here for too long, but to do that I needed to make sure the madder roots would leave the poor little girls alone. Turned into a pitched battle, as usual. But! I cleared a space for the irises, got some of them into the ground, and I will dig up some fresh bulbs on Thursday morning, to be sent Friday or Saturday.

Speaking of madder: I’ve enjoyed a bit of a milestone this spring, as for the first time I’ve made a madder lake from the roots I’ve grown in my own garden. All looked well, and for a while I was pretty excited. But when I mulled a bit of my new lake pigment up into an oil paint today after I returned from the garden, I found that the color is not as good as I had hoped. It’s darker and less saturated – almost maroon – and not nearly as bright as the madder lake I’d made from store-bought madder roots. Only when I apply the paint as a very thick glaze does it approach a decent red color.

Madder roots

Insistent madder roots

This is not at all good enough to justify all this trouble. Trouble! If you’ve never grown madder, then you can’t really understand what a royal pain the stuff has been. For evidence, just take a look at the board I happened to pull up today while digging for the roots. Yes, those are fresh madder roots pushing their way right through the board that I had put down there to stop them.

Also, even after you’ve fought the plants for years, and dug deep to get the roots out, it’s still a painstaking process after that to get a decent lake pigment from them. (At some point I’ll share my madder lake recipe, but not yet. There are still too many variations to try out before I’m sure of myself; and I’m still not sure if the recipe belongs here on this blog, or in a book. Or whether or not I’ll write a book at all.) So, if I can’t manage a better color than this, I’ll just go through the garden over a weekend and just rip them all out. Give the irises some more room.

madder lake swatches

madder lake swatches

To the right you can see two swatches of the madder lake from my garden, the two swatches at bottom. For comparison, I brushed out my previous madder lake, made from commercially-bought madder roots, above them. It’s not a really accurate pic, but you can see the difference. The lake from the garden isn’t horrible or anything – just not worth all the trouble.

I can think of three reasons why this color was not as good as the other I made. One, I made it a bit differently. (I don’t think that’s the reason.) Two, the earth in which the madder is growing may not be alkaline enough. (I doubt this is the reason either; the soil around here is pretty alkaline. But it’s possible.) Third, the roots from which I made this lake were too immature. This was a mixed batch of roots that were dug up at one and a half years and two years. I’m guessing – hoping – that’s the reason.

Madder roots

Madder roots from the garden

Today I dug up some roots that are clearly mature. They’ve been in the ground for about three years now. And just take a look at the size of some of those honking madder roots! I’ll be trying these out to see if there’s a substantial difference from the last batch, using exactly the recipe I used with the commercially-bought roots. Hopefully these will make something a lot closer to that one. If not, I’ll try amending the garden soil with lime or something. And if that doesn’t work, I may rip the things out and grow something easier instead. It would be disappointing – but kind of a relief too. I’ll report as I learn.

How to make a lake pigment

January 10, 2011

A basic lake pigment is pretty easy to make. Some lake pigments are more complex – there’s a reason madder lake took a while to catch on, historically – but most of them are easy as pie. It was noted recently in a comment that there is a dearth of comprehensible recipes online, and it’s true. It took me a bit of searching to figure out what things like “base,” “thrown down,” “precipitated onto,” and so on actually mean. But here is the basic process in all its simplicity. Let’s go:

Alum, washing soda

Alum, washing soda

First, what you’ll need. You’ll need alum, for starters – that’s potassium aluminum sulfate. This is the basic material that’s going to grab onto the dye color, just as it does when used as a mordant in fabric dyeing. You used to be able to get the stuff in the spice aisles of grocery stores, and apparently in some parts of the country you still can (it’s used in pickling cucumbers). I purchased mine from a dye shop. Also, you’ll need some kind of alkali to precipitate the alum (turn it into an insoluble powder). Some possibilities are potash (potassium carbonate), washing soda (sodium carbonate) or chalk (calcium carbonate). I use washing soda most often. You can get it from dye shops as well; but for a better deal grab a big container at Home Depot or Lowe’s in the pool section. On the right are these two items.

You’ll need the dyestuff itself. It’s worth noting here that not all dyes will grab onto alum to form a lake pigment; but if you’ve done a little research, you’ll have some idea at least of some of the ones used in the past. Here I’ll use some ripe buckthorn berries. These were most often inspissated to make the watercolor sap green; but the dye from them will make a lake pigment.

Cooking buckthorn berries

Cooking buckthorn berries

Equipment you’ll need: a pot and something to heat it with. On the right you see me heating up the berries in water on the stove. Some dyes, such as carmine, need to be boiled; for others, such as madder, boiling can ruin the color. Research and/or experiment. Other stuff: a funnel, some coffee filters and two jars of some sort (preserving jars work the best, because you don’t have to worry about pouring hot water into them). I usually have various jars around, so I can pour back and forth as needed. You’ll also need some distilled water – this is what should be used whenever the recipe calls for water. A mortar and pestle. And: a turkey baster. No, really.

Filtering the dye

Filtering the dye

Once your dye is extracted from the dyestuff, filter it, using the funnel and a coffee filter, over one of your jars. You need to get all the gunk out of there. Now that you’ve got some extracted and filtered dye, the magic can begin. Dissolve some alum in water on the stove (a pic of this can be seen here), then pour the warm alum solution into the dye jar. With some dyes, such as weld, this will immediately bring out the color; with others, you won’t see any difference.

Lake pigment precipitating

Lake pigment precipitating

Now, do the same thing with the alkali (be a little careful with potash or washing soda – these are alkaline enough to cause a burn, make sure to keep the stuff out of your eyes): dissolve some in water on the stove, then pour some of the solution into the dye. Right away you should get a fizzing reaction as the alum encounters the alkali: as the alkali precipitates the alum, it releases carbon dioxide (or something like that). How much of each, alum and alkali, should be used? Well, it’ll be different for each dye and each recipe. As a general thing it’s better to add too little than to add too much, as more can always be added later.

Precipitate settling

Precipitate settling

Let the jar sit – sometimes for a few hours, sometimes overnight – and the precipitate will eventually settle to the bottom. Now it should be washed a few times. Take your turkey baster (told ya) and siphon off the clear water on top, as much of it as you can without losing too much pigment. Then fill the jar back up with water and allow it to settle again. Do this as many times as it takes for the clear water to be colorless (or as near to that as your patience and water supply can handle!).

The filtrate

The filtrate

Once the water is colorless to your satisfaction, siphon it off one last time, and then you’ll filter the precipitate through the funnel and another coffee filter, into your other jar. The pigment will usually clog the filter, so you’ll need some patience for this: fill up the funnel, then go do something else for a while as it slowly drains, then come back and fill it up again, etc. If you’re making a larger batch of lake you may need more than one filter. Remove the filter containing lake and lay it flat on a surface – I use plates with paper towels, but bricks are supposed to work nicely – and give it a couple of days to dry (but don’t put it in the sun – these are fugitive colors here!). It will probably shrink in volume quite a bit as it loses moisture. Once the lake is completely dry, you can grind it up, thoroughly, using a mortar and pestle.

lake pigment

The lake pigment!

Now you have your pigment – mull it into linseed oil or gum arabic and give it a go! There’s very little more satisfying than creating a painting with your own pigments and paints. Don’t forget to keep good notes on your process – and feel free to post any questions or comments below.

Pigment categories – the blurry lines

December 26, 2010

It’s hard for me to believe that I’ve let my blog go for five whole weeks. I never thought I’d be one of those authors who had to post “Sorry it’s been so long since my last post” – and yet, here I am. Sorry, folks. It’s been a tough month. I’m abandoning for this post, and maybe the next post or two, the discussion of classical underpainting techniques; but I am continuing to research and experiment, faithful reader, and I’ll return to the topic soon.

Back to art materials philosophy. Some time back I listed some basic definitions for the four categories of artist’s pigments: natural inorganic, natural organic, synthetic inorganic, and synthetic organic. (See the posts here, here and here.) The categories seem straightforward enough once you become familiar with them. However, things can get a bit weird if you start trying to nail down certain pigments.

Take Prussian blue, which is considered a synthetic inorganic pigment, in fact the first modern synthetic pigment. This is a pigment discovered accidentally in the early eighteenth century while attempting to create a carmine lake pigment with what turned out to be some tainted substances. What happened was that some potash contaminated with animal blood was used to precipitate the iron-based lake pigment, accidentally forming iron ferrocyanine, which makes a powerful blue. (Lucky accident!) So, but here’s the question: how is it that when a natural organic lake pigment received an additional natural organic element, it turned into something that is considered a synthetic inorganic? Weird – why is this pigment not considered a natural organic, like the carmine lake? I suppose it’s because in Prussian blue there is no actual dye involved – but still, it seems arbitrary.

A lake pigment is generally thought of as a dye precipitated onto a base of alum; but as indicated above, not all lake pigments are based on alum. They can be based on iron or copper instead, or even other metal salts such as chrome or zinc. Sometimes, even when a natural dye is used, these lakes based on other metals are viewed as synthetic, or semi-synthetic, rather than natural. Why? Why is a natural dye laked onto alum considered a natural pigment, but the same natural dye laked onto copper may not be? Alum is potassium aluminum sulfate, the copper mordant is copper sulfate pentahydrate. Both are metal sulfates, pretty similar stuff. A dyer would consider any dye obtained from natural sources to be a natural dye, regardless of what mordant were used to bind it to fabric, be it alum, iron, copper, tin, chrome or other, and I would agree – and I don’t really think of natural dyes laked onto different metal substrates as being categorically different from one another.

Precipitating copper blue

Precipitating copper blue

But I can easily get myself into more trouble. Green and blue pigments can be made from copper without the addition of a natural dye, and yellow and red pigments can be made from iron – and these are also considered to be synthetic pigments. But why? If laking a natural dye onto alum, iron or copper results in a natural pigment, then why does it become synthetic if I follow exactly the same procedure, but only leave out the organic ingredient?

It’s at this point that the whole question starts to break down. One person to whom I mentioned my interest in natural pigments immediately quipped, “Well, what’s natural”? At the time I confess I was a little irritated by such a flippant-sounding dismissal of what has been a passion for me – but now I see the wisdom in it, regardless of how it may have been intended. What is natural, anyway? Don’t get me wrong: the words “natural” and “artificial” are opposites with real definitions; but as soon as we start trying to identify categories, we have to start drawing lines, and that’s where things get messy. At some point you have to chalk it up to useless semantics and move on to another aspect of the discussion.

This is all a little illustration of why, though my original direction (years ago, now) was almost entirely about natural pigments, and though I still write about my love for colors from natural sources, I now pay little attention to such distinctions when considering my philosophy of materials, just as I now pay little attention to toxicity (other than as a necessary practical concern). Natural, synthetic, doesn’t really matter. What does matter, to me, is whether a particular art material is sustainable – meaning that I think we artists will pretty much never be forced to stop using it. That means no industrial processes required in that material’s production, no hydrocarbon feedstocks are used, no destruction of landbases necessary – and we aren’t dependent for our materials upon the needs of the giant automobile, plastics and textiles industries. In a perfect world, that would mean art materials that could be made locally, from regionally common materials, and without harming the ecolocality in any drastic way. The only pigments that are categorically excluded from my list are the synthetic organics; they are derived from hydrocarbons, and really can’t be considered sustainable no matter how they’re sliced. Also excluded would be any other pigments that absolutely require an industrial process for production. The ones that would not be excluded are the natural earths; the natural organic colors; and artificial pigments easily synthesized from common metals and minerals.

Yes, this is the kind of thing I spend my time thinking about. I think it’s important.

– L. Lawrence

Pigment categories – Part I

December 21, 2009

Virtually all of the various artist’s pigments can be grouped into one of four categories, although there are a few that are not quite so easy to nail down. I’ll go through the different kinds, with a word or two about the history of each; I’ll mention a few of the borderline pigments in a later post. The four pigment categories are: natural inorganics; natural organics; synthetic inorganics (sounds almost like a double negative, doesn’t it?); and synthetic organics.

First are the natural inorganic pigments. These were some of the first in earliest human use, dating back many thousands of years and found in the cave paintings and hieroglyphs around the world. They are natural pigments that do not come from any organic source, neither plants nor animals. They are the earths, rocks, minerals, and crystals.

Wildcrafted natural earth pigment

Wildcrafted red ochre

Of these, the earths are particularly attractive to me. These are the yellow and red ochres, the siennas, the umbers and green earths. They are plentiful and varied, subtly beautiful and workhorse-ready. They seem to be an offering from the earth itself: look; take these and make your own works of wonder. For me, no other pigments give a closer connection with the natural world than the earths do. Other, brighter minerals are lapis lazuli, azurite, malachite, cinnabar, orpiment, turquoise. Some of these, such as cinnabar and orpiment, are quite toxic.

Natural organic pigments

Handcrafted natural organic pigments

Next are the natural organic pigments. These are pigments derived from plants and animals. This is the category that holds the most fascination for me, the one with which I spend the most time. The largest group of natural organic pigments are the lake pigments, which are natural dyes combined with a neutral metallic salt base to form insoluble pigments. These are rose madder, stil de grain, weld lake, carmine, etc. Other natural organic pigments are indigo, gamboge, carthamine red, vine black and eggshell white. The three powdered pigments in the picture to the right are, left to right: natural indigo mixed with calcite; brazilwood lake; and weld lake.

The natural organic pigments have given us some of the most beautiful and fascinating artist’s colors ever made. Most of them are also unfortunately impermanent to light – many of them drastically so, earning them the description “fugitive.” Even rose madder, which is far and away the most permanent natural organic lake pigment I know of, is today considered by many to be unacceptably impermanent for fine art work – though it was considered permanent by many in the past.

The natural organic and inorganic pigments are the categories I’ll be focusing on the most throughout this record, so it’s not necessary to write more about them just now – there will be plenty later. I’ll continue with the third and fourth categories in my next post. Happy holidays everyone!

L. Lawrence